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MetaCyc EC 1.14.14 -- With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

Parent Class: EC-Numbers1 -- Oxidoreductases1.14 -- Acting on paired donors, with incorporation or reduction of molecular oxygen

Instances:
1.14.14.1 -- unspecific monooxygenase,
1.14.14.3 -- alkanal monooxygenase (FMN),
1.14.14.5 -- alkanesulfonate monooxygenase,
1.14.14.8 -- anthranilate 3-monooxygenase (FAD),
1.14.14.9 -- 4-hydroxyphenylacetate 3-monooxygenase,
1.14.14.10 -- nitrilotriacetate monooxygenase,
1.14.14.11 -- styrene monooxygenase,
1.14.14.12 -- 3-hydroxy-9,10-secoandrosta-1,3,5(10)-triene-9,17-dione monooxygenase,
1.14.14.13 -- 4-(γ-L-glutamylamino)butanoyl-[BtrI acyl-carrier protein] monooxygenase,
1.14.14.14 -- aromatase,
1.14.14.15 -- (3S)-3-amino-3-(3-chloro-4-hydroxyphenyl)propanoyl-[peptidyl-carrier protein SgcC2] monooxygenase,
1.14.14.l -- steroid 21-monooxygenase,
1.14.14.m

Unofficial Reactions:
2,6-dichloro-p-hydroquinone + 2 FADH2 + oxygen → 6-chlorohydroxyquinol + chloride + 2 FAD + H2O + 2 H+,
3-dehydro-2,22,25-deoxyecdysone + a reduced flavoprotein + oxygen → 3-dehydro-2,22-dideoxyecdysone + an oxidized flavoprotein + H2O,
2,4,5-trichlorophenol + FADH2 + oxygen → 2,5-dichloro-p-quinone + chloride + FAD + H2O + H+,
2-methylpropanamine + a reduced flavin + oxygen → N-(2-methylpropyl)hydroxylamine + an oxidized flavin + H2O + H+,
(S)-β-tyrosyl-[SgcC2] + chloride + FADH2 + oxygen → (S)-3-chloro-β-tyrosyl-[SgcC2] + FAD + 2 H2O,
4-tyrosol + FADH2 + oxygen → 3-hydroxytyrosol + FAD + H2O + H+,
dimethyl sulfone + 2 FMNH2 + 2 oxygen → methanesulfonate + formaldehyde + 2 FMN + 2 H2O + 3 H+,
dibenzothiophene-5,5-dioxide + 2 FMNH2 + oxygen → 2'-hydroxybiphenyl-2-sulfinate + 2 FMN + H2O + 3 H+,
4-coumarate + FADH2 + oxygen → trans-caffeate + FAD + H2O + H+,
N'-hydroxymethyl-norcotinine + a reduced flavoprotein + oxygen → norcotinine + an oxidized flavoprotein + H2O,
3,5,6-trichloro-2-pyridinol + FADH2 + oxygen + 2 H2O → 3,6-dihydroxypyridine-2,5-dione + 3 chloride + FAD + H2O + 4 H+,
8-demethylnovobiocic acid + chloride + FADH2 + oxygen → clorobiocic acid + FAD + 2 H2O,
20-hydroxyecdysone + 3 a reduced flavoprotein + 3 oxygen → 20-hydroxyecdysonate + 3 an oxidized flavoprotein + 4 H2O + H+,
2,5-dichloro-p-quinol + FADH2 + oxygen → 5-chlorohydroxyquinone + chloride + FAD + H2O + 3 H+,
L-tyrosine + FADH2 + oxygen → L-dopa + FAD + H2O + H+,
2,22,25-trideoxyecdysone + a reduced flavoprotein + oxygen → 2,22-dideoxyecdysone + an oxidized flavoprotein + H2O,
dimethyl sulfone + FMNH2 + oxygen → methylsulfonyl + formaldehyde + FMN + H2O + H+

Enzymes and Genes:
cytochrome P450 306a1: phm ( Bombyx mori )
cytochrome P450 306a1: phm ( Drosophila melanogaster )
cytochrome P450 18a1: Cyp18a1 ( Drosophila melanogaster )
8-demethylnovobiocic acid halogenase: clo-hal ( Streptomyces roseochromogenus oscitans )
3,5,6-trichloro-2-pyridinol monooxygenase: tcpA ( Ralstonia sp. T6 )
dibenzothiophene-5,5-dioxide monooxygenase: dszA ( Rhodococcus YH3-3 )
dimethylsulfone monooxygenase: sfnG ( Pseudomonas putida DS1 )
4-coumarate 3-monooxygenase: hpaB ( Escherichia coli W )
isobutylamine N-hydroxylase: vlmH ( Streptomyces viridifaciens )
chlorophenol-4-monooxygenase: tftD ( Burkholderia phenoliruptrix )
cytochrome P450 306A1: phm ( Manduca sexta )
2,4,6-trichlorophenol monooxygenase / 2,6-dichlorohydroquinone monooxygenase: tcpA ( Ralstonia eutropha JMP134 )


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by Pathway Tools version 19.5 (software by SRI International) on Mon May 2, 2016, biocyc14.