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MetaCyc Reactions Class: Unknown Conversions

Summary:
Instances of this class define conversions for which it is not known whether the transformation occurs as a complex process or as a single reaction step. An example is the conversion of an inactive form of a protein to an active form, when the exact chemical forms of the protein, and the nature of the transition from one form to the other are not known. For transformations that are known to be multistep, use Complex-Processes class instead.

Parent Classes:
Reactions Classified By Conversion Type

Instances:
1.13.12.-: kauralexin A1 + oxygen → kauralexin A3 + H2O ,
1.13.12.-: kauralexin B1 + oxygen → kauralexin B3 + H2O ,
1.13.12.-: benzaldehyde + 2 NADPH + 2 oxygen + H+ → 6-hydroxy-2-cyclohexen-one-carboxylate + 2 NADP+ + H2O ,
1.14.13.-: ent-kaurene + NADPH + H+ + oxygen → kauralexin A1 + NADP+ + H2O ,
1.14.13.-: ent-isokaurene + NADPH + H+ + oxygen → kauralexin B1 + NADP+ + H2O ,
1.14.-.-: triferuloyl spermidine + 3 an reduced unknown electron acceptor + 3 oxygen → trihydroxyferuloyl spermidine + 3 an oxidized unknown electron acceptor + 3 H2O ,
1.14.-.-: tricoumaroyl spermidine + 3 an reduced unknown electron acceptor + 3 oxygen → tricaffeoyl spermidine + 3 an oxidized unknown electron acceptor + 3 H2O ,
2.1.1.-: tricaffeoyl spermidine + 3 S-adenosyl-L-methionine → triferuloyl spermidine + 3 S-adenosyl-L-homocysteine + 3 H+ ,
2.3.1.-: L-ornithine → L-Nδ-acetylornithine ,
2.3.1.-: 3 acetyl-CoA + a holo-[acyl-carrier protein] + 3 NADPH + 3 H+ → a triketide-[acp] + CO2 + 3 coenzyme A + 3 NADP+ + H2O ,
2.5.1.-: all-trans-hexaprenyl diphosphate + 1,4-dihydroxy-6-naphthoate + H+ → demethylmenaquinol-6 + CO2 + diphosphate ,
2.5.1.-: all-trans-octaprenyl diphosphate + 1,4-dihydroxy-6-naphthoate + H+ → CO2 + demethylmenaquinol-8 + diphosphate ,
3.5.4.-: 4-aminophenol + H2O + H+ → benzene-1,4-diol + ammonium ,
4.2.1.-: 2'-hydroxypyridoxol + an reduced unknown electron acceptor → pyridoxine + an oxidized unknown electron acceptor + H2O ,
3'-phospho-JI-20A + 2 an reduced unknown electron acceptor → gentamicin C1a + 2 an oxidized unknown electron acceptor + phosphate + H2O ,
3-propylidene-Δ 1-pyrroline-5-carboxylate → 4-propyl-L-proline ,
hexaketide pyrone + β-D-glucopyranose → aloenin ,
8-O-methylsterigmatocystin → aflatoxin G1 ,
3-amino-2-butanol + H2O + oxygen → 4 CO2 + ammonium ,
chrysanthemyl diphosphate + coenzyme A + H2O → (1R,3R)-chrysanthemoyl CoA + diphosphate ,
7-dehydrocholesterol → 14α-hydroxy-cholesta-4,7-diene-3,6-dione ,
6,7-O,O-dimethyl-N-deacetylisoipecoside aglycon → protoemetine ,
anthraniloyl-CoA ↔ benzoyl-CoA + ammonium ,
3 4-coumaryl-CoA + spermidine → tricoumaroyl spermidine + 3 coenzyme A + 3 H+ ,
8-O-methyldihydrosterigmatocystin → aflatoxin G2 ,
fructose 1,6-bisphosphate → norfuraneol ,
13'-hydroxy-α-tocopherol → 5'-α-carboxylmethylbutylhydroxychroman ,
trans-resveratrol = astringin ,
protopanaxadiol → ginsenoside Rd ,
1-methylxanthine → 1-methylurate ,
gentamicin A2 + S-adenosyl-L-methionine + L-glutamate + oxygen → gentamicin A + S-adenosyl-L-homocysteine + hydrogen peroxide + 2-oxoglutarate + H+ ,
dimethylsulfoniopropioyl-CoA + 2 H2O → dimethyl sulfide + 3-hydroxypropanoate + coenzyme A + 2 H+ ,
L-thyroxine = 3-iodothyronamine ,
Se-methyl-L-selenocysteine → dimethyl diselenide ,
presilphiperfolan-8β-ol + 2 oxygen → botrydial ,
gentamicin X2 + L-glutamate + oxygen → JI-20A + hydrogen peroxide + 2-oxoglutarate ,
4-[(1Z)-3-carboxylato-3-oxoprop-1-en-1-yl]-2,3-dihydro-1H-pyrrole-2-carboxylate → 3-propylidene-Δ 1-pyrroline-5-carboxylate ,
(S)-n-methylcanadine → secoberbine intermediate ,
5-phospho-β-D-ribosylamine → 2'-hydroxypyridoxol ,
(1E,6E)-1-(4-hydroxyphenyl)-7-phenylhepta-1,6-diene-3,5-dione + 2 an reduced unknown electron acceptor → (4E,6E)-1-(4-hydroxyphenyl)-7-phenylhepta-4,6-dien-3-one + 2 an oxidized unknown electron acceptor + H2O ,
4-(3-methylbut-2-enyl)-L-abrine + H2O → chanoclavine-I + CO2 ,
2-oxobutanoate → 5-hydroxy-2-oxopentanoate ,
S-norlaudanosoline + 3 S-adenosyl-L-methionine → (S)-reticuline + 3 S-adenosyl-L-homocysteine + 3 H+ ,
(+)-secoisolariciresinol → justicidin B ,
3-methylxanthine → 3-methylurate ,
oleanolate → ginsenoside Ro ,
3 feruloyl-CoA + spermidine → triferuloyl spermidine + 3 coenzyme A + 3 H+ ,
taxa-4(20),11-dien-5α,13α-diol → taxol ,
2-hydroxynaringenin + H+ ↔ naringenin dibenzoylmethane tautomer ,
2-methylbutanoyl-CoA → 2-methylbutanoate ,
versicolorin A → 6-demethylsterigmatocystin ,
G-418 + L-glutamate + oxygen → JI-20B + hydrogen peroxide + 2-oxoglutarate ,
versicolorin B → dihydrodemethylsterigmatocystin ,
6-pyruvoyl tetrahydropterin → 7,8-dihydropterin ,
(1R)-1,2,10,10a-tetrahydrophenazine-1-carboxylate + 2 an oxidized unknown electron acceptor → phenazine-1-carboxylate + 2 an reduced unknown electron acceptor ,
dTDP-β-L-rhamnose → dTDP-L-dihydrostreptose ,
2,5,7-trihydroxyflavanone + H+ ↔ 2,5,7-trihydroxyflavanone dibenzoylmethane tautomer ,
12-oxo-cis-10,15-phytodienoate → (S)-pyrethrolone ,
2 4-coumaroylagmatine + hydrogen peroxide → hordatine A + 2 H2O ,
theophylline = 1,3-dimethylurate ,
3 caffeoyl-CoA + spermidine → tricaffeoyl spermidine + 3 coenzyme A + 3 H+ ,
salvigenin → 8-hydroxy-salvigenin ,
5'-α-carboxylmethylbutylhydroxychroman → α-carboxyethylhydroxychroman ,
protopanaxatriol → ginsenoside Rg1 ,
2'-O-methyllicodione → echinatin ,
4,4'-diapolycopenedioate → 4,4'-diapolycopenedioate glycosyl diester ,
L-threonate → L-tartrate ,
3,5,3'-triiodo-L-thyronine → thyronamine ,
caffeine → 1,3,7-trimethylurate ,
10β-hydroxytaxa-4(20),11-dien-5α-yl acetate → 10-deacetyl-2-debenzoylbaccatin III ,
Δ2,5-3,4,4-trimethylpimeloyl-CoA + 3 coenzyme A + an oxidized unknown electron acceptor + H2O + H+ → isobutanoyl-CoA + 3 acetyl-CoA + an reduced unknown electron acceptor ,
presaframycin → saframycin A ,
2-methylbutanoate + pseudoisoeugenol → epoxypseudoisoeugenol-2-methylbutanoate ,
ent-2α-hydroxyisokaurene → oryzalide A ,
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-α -D- ribofuranosyl 5-phosphate]-D-ribitol + ATP → [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-α -D- ribofuranosyl triphosphate]-D-ribitol + AMP ,
fusarate → fusarinolate ,
4,5-O,O-dimethylthujaplicatin → yatein ,
12,13β-epoxy-16β-hydroxy-β-amyrin → monodeglucosyl des-acyl avenacin A ,
notoamide S → notoamide T ,
2-oxooctanoate → L-2-amino-8-hydroxyoctanoate ,
predesmethylbassianin A → desmethylbassianin ,
terpentetriene + 3 oxygen → terpentecin ,
an alkane → a secondary alcohol ,
fusicoccin J → fuscicoccin A ,
demethoxyfumitremorgin C → fumitremorgin C ,
trimethylaminoacetone + 2 NAD+ + H2O + oxygen → glycine betaine + CO2 + 2 NADH + 3 H+ ,
8β-hydroxy-germacra-1(10),4,11(13)-trien-12-oate → (+)-costunolide ,
2 2-imino-3-(indol-3-yl)propanoate + an oxidized unknown electron acceptor + 2 H+ → protodeoxyviolaceinate + ammonium + CO2 + an reduced unknown electron acceptor ,
echinocandin B nucleus → anidulafungin ,
rhizobactin 1021 core + a fatty acid → rhizobactin 1021 ,
asterriquinone C1 → terrequinone A ,
acetyl-CoA + 4 malonyl-CoA → L-2-aminodecanoate ,
a triketide-[acp] + oxaloacetate + ammonium → fusarate + a holo-[acyl-carrier protein] + 3 H2O ,
fusicocca-1,10(14)-diene-16-(hydroxymethyl)-3,8β-diol → brassicicene C ,
acetyl-CoA + 3 malonyl-CoA → 2-oxooctanoate ,
fusarate → methyl fusarate ,
20-hydroxy-fusarin → carboxy-fusarin C ,
5-oxo-2-furoyl-CoA + H2O → (2Z)-2-hydroxypent-2-enedioyl-CoA + H+ ,
GDP-D-erythro-α-D-gluco-octose → methylthiolincosamide ,
ammonium + ubiquinone-10 + H2O → rhodoquinone-10 + CO2 ,
7,2'-dihydroxy-4',5'-methylenedioxyisoflav-3-ene → (+)-6a-hydroxymaackiain ,
notoamide S → notoamide E ,
pluviatolide → podophyllotoxin ,
(-)-9β-pimara-7,15-dien-19-oate → 3β-hydroxy-9β-pimara-7,15-diene-19,6β-olide ,
gentisaldehyde → isoepoxydon ,
acetyl-CoA + 2 an oxidized unknown electron acceptor + 2 H2O → glyoxylate + coenzyme A + 2 an reduced unknown electron acceptor + H+ ,
echinocandin B nucleus → cilofungin ,
12,13β-epoxy-16β-hydroxy-β-amyrin = des-acyl avenacin A ,
2α-hydroxy-ent-cassadiene → 2β,3β-dihydroxy-12,15-cassadiene-11-one ,
artemisinate → artemisinin ,
3-hydroxy-2-oxo-indole-3-acetate + an reduced unknown electron acceptor → 3-hydroxyindolin-2-one + acetate + an oxidized unknown electron acceptor ,
L-lysine → 1-piperideine 6-carboxylate ,
fusarate → 9,10-dehydrofusarate ,
yatein → deoxypodophyllotoxin ,
ent-11β-hydroxycassa-12,15-diene → 3β-hydroxy-12,15-cassadiene-11-one ,
3α-hydroxy-ent-cassadiene → 3β-hydroxy-12,15-cassadiene-11-one ,
fusicocca-2,10(14)-diene → fusicocca-2,10(14)-diene-8β,16-diol ,
notoamide T → stephacidin A ,
2,4-dihydroxybenzoate + all-trans-hexaprenyl diphosphate + 2 S-adenosyl-L-methionine + 2 NADPH + 2 oxygen + H+ → 3-demethylubiquinol-6 + 2 S-adenosyl-L-homocysteine + CO2 + 2 NADP+ + diphosphate + 2 H2O ,
3-(4-sulfophenyl)butanoate → 4-sulfoacetophenone ,
L-2-amino-8-hydroxyoctanoate → L-2-aminooctanedioate ,
(-)-maackiain → (+)-maackiain ,
ubiquinone-9 + ammonium + H2O → rhodoquinone-9 + CO2 ,
prebassianin A → bassianin ,
6β-hydroxy-syn-pimaradiene → 3β-hydroxy-9β-pimara-7,15-diene-19,6β-olide ,
fusicocca-1,10(14)-diene-8β,16-diol → fusicoccin P ,
N-acetyl-D-galactosaminyl-(1→4)-β-D-glucuronyl-(1→3)-β-N-acetyl-D-galactosaminyl-(1→4)-β-D-glucuronyl-(1→3)-β-D-galactosyl-(1->3)-β-D-galactosyl-(1->4)-β-D-xylosyl-[core protein] → chondroitin-[core protein] ,
a 8-(3-amino-5-hydroxyphenyl)-8-hydroxy-3,7-dimethyloctane-2,4,6-trione -[PKS-acp] → a 3-amino-8-[(2E)-2,4-dimethyl-5-oxohex-2-enoyl]-5,7-dihydroxy-6-methyl-1,4,5,6-tetrahydronaphthalene-1,4-dione -[PKS-acp] ,
3-benzyl-3,6 -disulfide-6-(hydroxymethyl)-diketopiperazine → N-desmethyl-gliotoxin


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 19.0 on Sat Aug 29, 2015, biocyc12.