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MetaCyc Reactions Class: Unknown Conversions

Summary:
Instances of this class define conversions for which it is not known whether the transformation occurs as a complex process or as a single reaction step. An example is the conversion of an inactive form of a protein to an active form, when the exact chemical forms of the protein, and the nature of the transition from one form to the other are not known. For transformations that are known to be multistep, use Complex-Processes class instead.

Parent Classes:
Reactions Classified By Conversion Type

Instances:
1.13.12.-: benzaldehyde + 2 NADPH + 2 oxygen + H+ → 6-hydroxy-2-cyclohexen-one-carboxylate + 2 NADP+ + H2O ,
1.13.12.-: kauralexin B1 + oxygen → kauralexin B3 + H2O ,
1.13.12.-: kauralexin A1 + oxygen → kauralexin A3 + H2O ,
1.14.13.-: ent-isokaurene + NADPH + H+ + oxygen → kauralexin B1 + NADP+ + H2O ,
1.14.13.-: ent-kaurene + NADPH + H+ + oxygen → kauralexin A1 + NADP+ + H2O ,
1.14.-.-: triferuloyl spermidine + 3 an unknown reduced electron acceptor + 3 oxygen → trihydroxyferuloyl spermidine + 3 an unknown oxidized electron acceptor + 3 H2O ,
1.14.-.-: tricoumaroyl spermidine + 3 an unknown reduced electron acceptor + 3 oxygen → tricaffeoyl spermidine + 3 an unknown oxidized electron acceptor + 3 H2O ,
2.1.1.-: tricaffeoyl spermidine + 3 S-adenosyl-L-methionine → triferuloyl spermidine + 3 S-adenosyl-L-homocysteine + 3 H+ ,
2.3.1.-: L-ornithine → L-Nδ-acetylornithine ,
2.5.1.-: all-trans-hexaprenyl diphosphate + 1,4-dihydroxy-6-naphthoate + H+ → demethylmenaquinol-6 + CO2 + diphosphate ,
2.5.1.-: all-trans-octaprenyl diphosphate + 1,4-dihydroxy-6-naphthoate + H+ → CO2 + demethylmenaquinol-8 + diphosphate ,
3.5.4.-: 4-aminophenol + H2O + H+ → benzene-1,4-diol + ammonium ,
4.2.1.-: 2'-hydroxypyridoxol + an unknown reduced electron acceptor → pyridoxine + an unknown oxidized electron acceptor + H2O ,
5-oxo-2-furoyl-CoA + H2O → (2Z)-2-hydroxypent-2-enedioyl-CoA + H+ ,
8β-hydroxy-germacra-1(10),4,11(13)-trien-12-oate → (+)-costunolide ,
demethoxyfumitremorgin C → fumitremorgin C ,
fusicoccin J → fuscicoccin A ,
ubiquinone-9 + ammonium + H2O → rhodoquinone-9 + CO2 ,
Δ2,5-3,4,4-trimethylpimeloyl-CoA + 3 coenzyme A + an unknown oxidized electron acceptor + H2O + H+ → isobutanoyl-CoA + 3 acetyl-CoA + an unknown reduced electron acceptor ,
2 2-imino-3-(indol-3-yl)propanoate + an unknown oxidized electron acceptor + 2 H+ → protodeoxyviolaceinate + ammonium + CO2 + an unknown reduced electron acceptor ,
predesmethylbassianin A → desmethylbassianin ,
2,4-dihydroxybenzoate + all-trans-hexaprenyl diphosphate + 2 S-adenosyl-L-methionine + 2 NADPH + 2 oxygen + H+ → 3-demethylubiquinol-6 + 2 S-adenosyl-L-homocysteine + CO2 + 2 NADP+ + diphosphate + 2 H2O ,
notoamide S → notoamide T ,
3-hydroxy-2-oxo-indole-3-acetate + an unknown reduced electron acceptor → 3-hydroxyindolin-2-one + acetate + an unknown oxidized electron acceptor ,
an alkane → a secondary alcohol ,
ent-2α-hydroxyisokaurene → oryzalide A ,
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-α -D- ribofuranosyl 5-phosphate]-D-ribitol + ATP → [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-α -D- ribofuranosyl triphosphate]-D-ribitol + AMP ,
12,13β-epoxy-16β-hydroxy-β-amyrin = des-acyl avenacin A ,
acetyl-CoA + 2 an unknown oxidized electron acceptor + 2 H2O → glyoxylate + coenzyme A + 2 an unknown reduced electron acceptor + H+ ,
fusicocca-1,10(14)-diene-8β,16-diol → fusicoccin P ,
ammonium + ubiquinone-10 + H2O → rhodoquinone-10 + CO2 ,
(-)-9β-pimara-7,15-dien-19-oate → 3β-hydroxy-9β-pimara-7,15-diene-19,6β-olide ,
prebassianin A → bassianin ,
3-(4-sulfophenyl)butyrate → 4-sulfoacetophenone ,
notoamide T → stephacidin A ,
fusicocca-2,10(14)-diene → fusicocca-2,10(14)-diene-8β,16-diol ,
6β-hydroxy-syn-pimaradiene → 3β-hydroxy-9β-pimara-7,15-diene-19,6β-olide ,
ent-11β-hydroxycassa-12,15-diene → 3β-hydroxy-12,15-cassadiene-11-one ,
3α-hydroxy-ent-cassadiene → 3β-hydroxy-12,15-cassadiene-11-one ,
rhizobactin 1021 core + a fatty acid → rhizobactin 1021 ,
artemisinate → artemisinin ,
2α-hydroxy-ent-cassadiene → 2β,3β-dihydroxy-12,15-cassadiene-11-one ,
trimethylaminoacetone + 2 NAD+ + H2O + oxygen → glycine betaine + CO2 + 2 NADH + 3 H+ ,
terpentetriene + 3 oxygen → terpentecin ,
gentisaldehyde → isoepoxydon ,
notoamide S → notoamide E ,
2-methylbutanoate + pseudoisoeugenol → epoxypseudoisoeugenol-2-methylbutyrate ,
GDP-D-erythro-α-D-gluco-octose → methylthiolincosamide ,
fusicocca-1,10(14)-diene-16-(hydroxymethyl)-3,8β-diol → brassicicene C ,
12,13β-epoxy-16β-hydroxy-β-amyrin → monodeglucosyl des-acyl avenacin A ,
asterriquinone C1 → terrequinone A ,
3-benzyl-3,6 -disulfide-6-(hydroxymethyl)-diketopiperazine → N-desmethyl-gliotoxin ,
a 8-(3-amino-5-hydroxyphenyl)-8-hydroxy-3,7-dimethyloctane-2,4,6-trione -[PKS-acp] → a 3-amino-8-[(2E)-2,4-dimethyl-5-oxohex-2-enoyl]-5,7-dihydroxy-6-methyl-1,4,5,6-tetrahydronaphthalene-1,4-dione -[PKS-acp] ,
N-acetyl-D-galactosaminyl-(1→4)-β-D-glucuronyl-(1→3)-β-N-acetyl-D-galactosaminyl-(1→4)-β-D-glucuronyl-(1→3)-β-D-galactosyl-(1->3)-β-D-galactosyl-(1->4)-β-D-xylosyl-[core protein] = chondroitin ,
chrysanthemyl diphosphate + coenzyme A + H2O → (1R,3R)-chrysanthemoyl CoA + diphosphate ,
(1R)-1,2,10,10a-tetrahydrophenazine-1-carboxylate + 2 an unknown oxidized electron acceptor → phenazine-1-carboxylate + 2 an unknown reduced electron acceptor ,
G-418 + L-glutamate + oxygen → JI-20B + hydrogen peroxide + 2-oxoglutarate ,
7-dehydrocholesterol → 14α-hydroxy-cholesta-4,7-diene-3,6-dione ,
3-propylidene-Δ 1-pyrroline-5-carboxylate → 4-propyl-L-proline ,
6,7-O,O-dimethyl-N-deacetylisoipecoside aglycon → protoemetine ,
3-methylxanthine → 3-methylurate ,
3 feruloyl-CoA + spermidine → triferuloyl spermidine + 3 coenzyme A + 3 H+ ,
3-amino-2-butanol + H2O + oxygen → 4 CO2 + ammonium ,
L-threonate → L-tartrate ,
dimethylsulfoniopropioyl-CoA + 2 H2O → dimethyl sulfide + 3-hydroxypropanoate + coenzyme A + 2 H+ ,
8-O-methyldihydrosterigmatocystin → aflatoxin G2 ,
(1E,6E)-1-(4-hydroxyphenyl)-7-phenylhepta-1,6-diene-3,5-dione + 2 an unknown reduced electron acceptor → (4E,6E)-1-(4-hydroxyphenyl)-7-phenylhepta-4,6-dien-3-one + 2 an unknown oxidized electron acceptor + H2O ,
protopanaxatriol → ginsenoside Rg1 ,
protopanaxadiol → ginsenoside Rd ,
anthraniloyl-CoA ↔ benzoyl-CoA + ammonium ,
fructose 1,6-bisphosphate → norfuraneol ,
salvigenin → 8-hydroxy-salvigenin ,
12-oxo-cis-10,15-phytodienoate → (S)-pyrethrolone ,
8-O-methylsterigmatocystin → aflatoxin G1 ,
gentamicin X2 + L-glutamate + oxygen → JI-20A + hydrogen peroxide + 2-oxoglutarate ,
1-methylxanthine → 1-methylurate ,
2,5,7-trihydroxyflavanone + H+ ↔ 2,5,7-trihydroxyflavanone dibenzoylmethane tautomer ,
Se-methyl-L-selenocysteine → dimethyl diselenide ,
L-thyroxine = 3-iodothyronamine ,
gentamicin A2 + S-adenosyl-L-methionine + L-glutamate + oxygen → gentamicin A + S-adenosyl-L-homocysteine + hydrogen peroxide + 2-oxoglutarate + H+ ,
3 4-coumaryl-CoA + spermidine → tricoumaroyl spermidine + 3 coenzyme A + 3 H+ ,
10β-hydroxytaxa-4(20),11-dien-5α-yl acetate → 10-deacetyl-2-debenzoylbaccatin III ,
presilphiperfolan-8β-ol + 2 oxygen → botrydial ,
13'-hydroxy-α-tocopherol → 5'-α-carboxylmethylbutylhydroxychroman ,
6-pyruvoyl tetrahydropterin → 7,8-dihydropterin ,
2-methylbutanoyl-CoA → 2-methylbutanoate ,
4-(3-methylbut-2-enyl)-L-abrine + H2O → chanoclavine-I + CO2 ,
dTDP-β-L-rhamnose → dTDP-L-dihydrostreptose ,
2-hydroxynaringenin + H+ ↔ naringenin dibenzoylmethane tautomer ,
(+)-secoisolariciresinol → justicidin B ,
oleanolate → ginsenoside Ro ,
versicolorin B → dihydrodemethylsterigmatocystin ,
3'-phospho-JI-20A + 2 an unknown reduced electron acceptor → gentamicin C1a + 2 an unknown oxidized electron acceptor + phosphate + H2O ,
versicolorin A → 6-demethylsterigmatocystin ,
hexaketide pyrone + β-D-glucose → aloenin ,
caffeine → 1,3,7-trimethylurate ,
3,5,3'-triiodo-L-thyronine → thyronamine ,
4-[(1Z)-3-carboxylato-3-oxoprop-1-en-1-yl]-2,3-dihydro-1H-pyrrole-2-carboxylate → 3-propylidene-Δ 1-pyrroline-5-carboxylate ,
2'-O-methyllicodione → echinatin ,
theophylline = 1,3-dimethylurate ,
3 caffeoyl-CoA + spermidine → tricaffeoyl spermidine + 3 coenzyme A + 3 H+ ,
5-phospho-β-D-ribosylamine → 2'-hydroxypyridoxol ,
5'-α-carboxylmethylbutylhydroxychroman → α-carboxyethylhydroxychroman ,
4,4'-diapolycopenedioate → 4,4'-diapolycopenedioate glycosyl diester ,
2 4-coumaroylagmatine + hydrogen peroxide → hordatine A + 2 H2O ,
S-norlaudanosoline + 3 S-adenosyl-L-methionine → (S)-reticuline + 3 S-adenosyl-L-homocysteine + 3 H+ ,
taxa-4(20),11-dien-5α,13α-diol → taxol ,
trans-resveratrol = astringin ,
(S)-n-methylcanadine → secoberbine intermediate ,
2-oxobutanoate → 5-hydroxy-2-oxopentanoate


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Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 19.0 on Thu May 28, 2015, BIOCYC14B.