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MetaCyc Reactions Class: Unknown Conversions

Summary:
Instances of this class define conversions for which it is not known whether the transformation occurs as a complex process or as a single reaction step. An example is the conversion of an inactive form of a protein to an active form, when the exact chemical forms of the protein, and the nature of the transition from one form to the other are not known. For transformations that are known to be multistep, use Complex-Processes class instead.

Parent Classes:
Reactions Classified By Conversion Type

Instances:
1.13.12.-: kauralexin B1 + oxygen → kauralexin B3 + H2O,
1.13.12.-: kauralexin A1 + oxygen → kauralexin A3 + H2O,
1.13.12.-: benzaldehyde + 2 NADPH + 2 oxygen + H+ → 6-hydroxy-2-cyclohexen-one-carboxylate + 2 NADP+ + H2O,
1.14.13.-: ent-isokaurene + NADPH + H+ + oxygen → kauralexin B1 + NADP+ + H2O,
1.14.13.-: ent-kaurene + NADPH + H+ + oxygen → kauralexin A1 + NADP+ + H2O,
1.14.-.-: triferuloyl spermidine + 3 an reduced unknown electron acceptor + 3 oxygen → trihydroxyferuloyl spermidine + 3 an oxidized unknown electron acceptor + 3 H2O,
1.14.-.-: tricoumaroyl spermidine + 3 an reduced unknown electron acceptor + 3 oxygen → tricaffeoyl spermidine + 3 an oxidized unknown electron acceptor + 3 H2O,
2.1.1.-: tricaffeoyl spermidine + 3 S-adenosyl-L-methionine → triferuloyl spermidine + 3 S-adenosyl-L-homocysteine + 3 H+,
2.3.1.-: L-ornithine → L-Nδ-acetylornithine,
2.3.1.-: 3 acetyl-CoA + a holo-[acyl-carrier protein] + 3 NADPH + 3 H+ → a triketide-[acp] + CO2 + 3 coenzyme A + 3 NADP+ + H2O,
2.5.1.-: all-trans-octaprenyl diphosphate + 1,4-dihydroxy-6-naphthoate + H+ → demethylmenaquinol-8 + CO2 + diphosphate,
2.5.1.-: all-trans-hexaprenyl diphosphate + 1,4-dihydroxy-6-naphthoate + H+ → demethylmenaquinol-6 + CO2 + diphosphate,
3.5.4.-: 4-aminophenol + H2O + H+ → benzene-1,4-diol + ammonium,
4.2.1.-: 2'-hydroxypyridoxol + an reduced unknown electron acceptor → pyridoxine + an oxidized unknown electron acceptor + H2O,
ubiquinone-10 + ammonium + H2O → rhodoquinone-10 + CO2,
a triketide-[acp] + oxaloacetate + ammonium → fusarate + a holo-[acyl-carrier protein] + 3 H2O,
acetyl-CoA + 4 malonyl-CoA → L-2-aminodecanoate,
echinocandin B nucleus → anidulafungin,
trimethylaminoacetone + 2 NAD+ + H2O + oxygen → glycine betaine + CO2 + 2 NADH + 3 H+,
5-oxo-2-furoyl-CoA + H2O → (2Z)-2-hydroxypent-2-enedioyl-CoA + H+,
fusicocca-1,10(14)-diene-8β,16-diol → fusicoccin P,
15-acetyldeoxynivalenol → deoxynivalenol,
notoamide T → stephacidin A,
fusicocca-2,10(14)-diene → fusicocca-2,10(14)-diene-8β,16-diol,
2 2-imino-3-(indol-3-yl)propanoate + an oxidized unknown electron acceptor + 2 H+ → protodeoxyviolaceinate + ammonium + CO2 + an reduced unknown electron acceptor,
6β-hydroxy-syn-pimaradiene → 3β-hydroxy-9β-pimara-7,15-diene-19,6β-olide,
ent-11β-hydroxycassa-12,15-diene → 3β-hydroxy-12,15-cassadiene-11-one,
prebassianin A → bassianin,
3-(4-sulfophenyl)butanoate → 4-sulfoacetophenone,
terpentetriene + 3 oxygen → terpentecin,
3α-hydroxy-ent-cassadiene → 3β-hydroxy-12,15-cassadiene-11-one,
yatein → deoxypodophyllotoxin,
2-oxooctanoate → L-2-amino-8-hydroxyoctanoate,
4-acetylnivalenol → nivalenol,
artemisinate → artemisinin,
2α-hydroxy-ent-cassadiene → 2β,3β-dihydroxy-12,15-cassadiene-11-one,
fusarate → fusarinolate,
12,13β-epoxy-16β-hydroxy-β-amyrin = des-acyl avenacin A,
2-methylbutanoate + pseudoisoeugenol → epoxypseudoisoeugenol-2-methylbutanoate,
presaframycin → saframycin A,
gentisaldehyde → isoepoxydon,
8-O-methyl-fusarubinlactone → 8-O-methylanhydrofusarubinlactol,
hexaketide pyrone + D-glucopyranose → aloenin,
2,4-dihydroxybenzoate + all-trans-hexaprenyl diphosphate + 2 S-adenosyl-L-methionine + 2 NADPH + 2 oxygen + H+ → 3-demethylubiquinol-6 + 2 S-adenosyl-L-homocysteine + CO2 + 2 NADP+ + diphosphate + 2 H2O,
8-O-methylfusarubin alcohol → 8-O-methylnectriafurone,
(-)-9β-pimara-7,15-dien-19-oate → 3β-hydroxy-9β-pimara-7,15-diene-19,6β-olide,
pluviatolide → podophyllotoxin,
Δ2,5-3,4,4-trimethylpimeloyl-CoA + 3 coenzyme A + an oxidized unknown electron acceptor + H2O + H+ → isobutanoyl-CoA + 3 acetyl-CoA + an reduced unknown electron acceptor,
notoamide S → notoamide E,
fusicocca-1,10(14)-diene-16-(hydroxymethyl)-3,8β-diol → brassicicene C,
GDP-D-erythro-α-D-gluco-octose → methylthiolincosamide,
L-2-amino-8-hydroxyoctanoate → L-2-aminooctanedioate,
asterriquinone C1 → terrequinone A,
an alkane → a secondary alcohol,
3-hydroxy-2-oxo-indole-3-acetate + an reduced unknown electron acceptor → 3-hydroxyindolin-2-one + acetate + an oxidized unknown electron acceptor,
2-hydroxynaringenin ↔ naringenin dibenzoylmethane tautomer,
ubiquinone-9 + ammonium + H2O → rhodoquinone-9 + CO2,
fusarate → 9,10-dehydrofusarate,
L-lysine → 1-piperideine 6-carboxylate,
5-methoxy-6-methylbenzimidazole → 5,6-dimethylbenzimidazole,
8β-hydroxy-germacra-1(10),4,11(13)-trien-12-oate → (+)-costunolide,
rhizobactin 1021 core + a fatty acid → rhizobactin 1021,
phomopsene → methyl phomopsenoate,
fusicoccin J → fuscicoccin A,
7,8-dihydroxy-3,4,15-triacetoxyscirpenol → 3,4,15-triacetylnivalenol,
echinocandin B nucleus → cilofungin,
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-α -D- ribofuranosyl 5-phosphate]-D-ribitol + ATP → [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-α -D- ribofuranosyl triphosphate]-D-ribitol + AMP,
8-O-methyl-13-carboxynorjavanicin → 8-O-methyl-13-hydroxynorjavanicin + CO2,
acetyl-CoA + 2 an oxidized unknown electron acceptor + 2 H2O → glyoxylate + coenzyme A + 2 an reduced unknown electron acceptor + H+,
demethoxyfumitremorgin C → fumitremorgin C,
3-acetyldeoxynivalenol → deoxynivalenol,
8-O-methylfusarubinaldehyde → 8-O-methyl-13-carboxynorjavanicin,
ferruginol → carnosate,
notoamide S → notoamide T,
7,8-dihydroxycalonectrin → 3,15-acetyldeoxynivalenol,
7,2'-dihydroxy-4',5'-methylenedioxyisoflav-3-ene → (+)-6a-hydroxymaackiain,
predesmethylbassianin A → desmethylbassianin,
(-)-maackiain → (+)-maackiain,
ent-2α-hydroxyisokaurene → oryzalide A,
12,13β-epoxy-16β-hydroxy-β-amyrin → monodeglucosyl des-acyl avenacin A,
4,5-O,O-dimethylthujaplicatin → yatein,
20-hydroxy-fusarin → carboxy-fusarin C,
fusarate → methyl fusarate,
acetyl-CoA + 3 malonyl-CoA → 2-oxooctanoate,
N-acetyl-D-galactosaminyl-(1→4)-β-D-glucuronyl-(1→3)-β-N-acetyl-D-galactosaminyl-(1→4)-β-D-glucuronyl-(1→3)-β-D-galactosyl-(1->3)-β-D-galactosyl-(1->4)-β-D-xylosyl-[core protein] → chondroitin-[core protein],
3-benzyl-3,6 -disulfide-6-(hydroxymethyl)-diketopiperazine → N-desmethyl-gliotoxin,
a 8-(3-amino-5-hydroxyphenyl)-8-hydroxy-3,7-dimethyloctane-2,4,6-trione -[PKS-acp] → a 3-amino-8-[(2E)-2,4-dimethyl-5-oxohex-2-enoyl]-5,7-dihydroxy-6-methyl-1,4,5,6-tetrahydronaphthalene-1,4-dione -[PKS-acp],
fructose 1,6-bisphosphate → norfuraneol,
8-O-methyldihydrosterigmatocystin → aflatoxin G2,
6,7-O,O-dimethyl-N-deacetylisoipecoside aglycon → protoemetine,
2-oxobutanoate → 5-hydroxy-2-oxopentanoate,
5-phospho-β-D-ribosylamine → 2'-hydroxypyridoxol,
presilphiperfolan-8β-ol + 2 oxygen → botrydial,
L-thyroxine = 3-iodothyronamine,
4-[(1Z)-3-carboxylato-3-oxoprop-1-en-1-yl]-2,3-dihydro-1H-pyrrole-2-carboxylate → 3-propylidene-Δ 1-pyrroline-5-carboxylate,
7-dehydrocholesterol → 14α-hydroxy-cholesta-4,7-diene-3,6-dione,
gentamicin X2 + L-glutamate + oxygen → JI-20A + hydrogen peroxide + 2-oxoglutarate,
3 feruloyl-CoA + spermidine → triferuloyl spermidine + 3 coenzyme A + 3 H+,
1-methylxanthine → 1-methylurate,
8-O-methylsterigmatocystin → aflatoxin G1,
gentamicin A2 + S-adenosyl-L-methionine + L-glutamate + oxygen → gentamicin A + S-adenosyl-L-homocysteine + hydrogen peroxide + 2-oxoglutarate + H+,
3-amino-2-butanol + H2O + oxygen → 4 CO2 + ammonium,
taxa-4(20),11-dien-5α,13α-diol → taxol,
trans-resveratrol = astringin,
(1E,6E)-1-(4-hydroxyphenyl)-7-phenylhepta-1,6-diene-3,5-dione + 2 an reduced unknown electron acceptor → (4E,6E)-1-(4-hydroxyphenyl)-7-phenylhepta-4,6-dien-3-one + 2 an oxidized unknown electron acceptor + H2O,
protopanaxatriol → ginsenoside Rg1,
4-(3-methylbut-2-enyl)-L-abrine + H2O → chanoclavine-I + CO2,
chrysanthemyl diphosphate + coenzyme A + H2O → (1R,3R)-chrysanthemoyl CoA + diphosphate,
2,5,7-trihydroxyflavanone + H+ ↔ 2,5,7-trihydroxyflavanone dibenzoylmethane tautomer,
S-norlaudanosoline + 3 S-adenosyl-L-methionine → (S)-reticuline + 3 S-adenosyl-L-homocysteine + 3 H+,
anthraniloyl-CoA ↔ benzoyl-CoA + ammonium,
salvigenin → 8-hydroxy-salvigenin,
dTDP-β-L-rhamnose → dTDP-L-dihydrostreptose,
3,5,3'-triiodo-L-thyronine → thyronamine,
3-propylidene-Δ 1-pyrroline-5-carboxylate → 4-propyl-L-proline,
3'-phospho-JI-20A + 2 an reduced unknown electron acceptor → gentamicin C1a + 2 an oxidized unknown electron acceptor + phosphate + H2O,
versicolorin B → dihydrodemethylsterigmatocystin,
Se-methyl-L-selenocysteine → dimethyl diselenide,
6-pyruvoyl tetrahydropterin → 7,8-dihydropterin,
L-threonate → L-tartrate,
4,4'-diapolycopenedioate → 4,4'-diapolycopenedioate glycosyl diester,
3 4-coumaryl-CoA + spermidine → tricoumaroyl spermidine + 3 coenzyme A + 3 H+,
theophylline = 1,3-dimethylurate,
versicolorin A → 6-demethylsterigmatocystin,
13'-hydroxy-α-tocopherol → 5'-α-carboxylmethylbutylhydroxychroman,
protopanaxadiol → ginsenoside Rd,
2-methylbutanoyl-CoA → 2-methylbutanoate,
12-oxo-cis-10,15-phytodienoate → (S)-pyrethrolone,
oleanolate → ginsenoside Ro,
(1R)-1,2,10,10a-tetrahydrophenazine-1-carboxylate + 2 an oxidized unknown electron acceptor → phenazine-1-carboxylate + 2 an reduced unknown electron acceptor,
G-418 + L-glutamate + oxygen → JI-20B + hydrogen peroxide + 2-oxoglutarate,
caffeine → 1,3,7-trimethylurate,
(S)-n-methylcanadine → secoberbine intermediate,
2'-O-methyllicodione → echinatin,
3 trans-caffeoyl-CoA + spermidine → tricaffeoyl spermidine + 3 coenzyme A + 3 H+,
3-methylxanthine → 3-methylurate,
10β-hydroxytaxa-4(20),11-dien-5α-yl acetate → 10-deacetyl-2-debenzoylbaccatin III,
5'-α-carboxylmethylbutylhydroxychroman → α-carboxyethylhydroxychroman,
(+)-secoisolariciresinol → justicidin B,
dimethylsulfoniopropioyl-CoA + 2 H2O → dimethyl sulfide + 3-hydroxypropanoate + coenzyme A + 2 H+,
2 4-coumaroylagmatine + hydrogen peroxide → hordatine A + 2 H2O


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Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
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