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Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
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MetaCyc Compound: phosphinopyruvate

Synonyms: 3-[hydroxy(oxido)phosphoranyl]pyruvic acid, 3-(hydrohydroxyphosphoryl)pyruvate, (hydroxyphosphinyl)pyruvate, PPA, 3-hydrohydroxyphosphorylpyruvate

Superclasses: an organophosphorus compound a phosphinate

Citations: [Blodgett05]

Chemical Formula: C3H3O5P

Molecular Weight: 149.02 Daltons

Monoisotopic Molecular Weight: 151.987459781 Daltons

SMILES: C([O-])(=O)C(=O)CP([O-])=O

InChI: InChI=1S/C3H5O5P/c4-2(3(5)6)1-9(7)8/h9H,1H2,(H,5,6)(H,7,8)/p-2

InChIKey: InChIKey=VHAFWRWGHGSZDL-UHFFFAOYSA-L

Unification Links: CAS:144705-32-8 , ChEBI:58348 , ChemSpider:10306741 , KEGG:C06368 , PubChem:21722341

Standard Gibbs Free Energy of Change Formation (ΔfG in kcal/mol): -153.72601 Inferred by computational analysis [Latendresse13]

Reactions known to consume the compound:

phosphinothricin tripeptide biosynthesis :
phosphinopyruvate + acetyl-CoA + H2O → phosphinomethylmalate + coenzyme A + H+

Reactions known to produce the compound:

phosphinothricin tripeptide biosynthesis :
carboxyphosphinopyruvate → phosphinopyruvate + CO2

In Reactions of unknown directionality:

Not in pathways:
carboxyphosphonoenolpyruvate = CO2 + phosphinopyruvate

Credits:
Created 25-Aug-2009 by Caspi R , SRI International


References

Blodgett05: Blodgett JA, Zhang JK, Metcalf WW (2005). "Molecular cloning, sequence analysis, and heterologous expression of the phosphinothricin tripeptide biosynthetic gene cluster from Streptomyces viridochromogenes DSM 40736." Antimicrob Agents Chemother 49(1);230-40. PMID: 15616300

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 18.5 on Mon Dec 22, 2014, biocyc13.