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Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
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MetaCyc Compound: 16α, 17-epoxy gibberellin A9

Synonyms: 16α, 17-epoxy GA9

Superclasses: a hormone a plant hormone a gibberellin
a lipid an isoprenoid a terpenoid a diterpenoid a gibberellin
a secondary metabolite a terpenoid a diterpenoid a gibberellin

Citations: [Zhu06a]

Chemical Formula: C19H23O5

Molecular Weight: 331.39 Daltons

Monoisotopic Molecular Weight: 332.1623738809 Daltons

SMILES: CC12(CCCC3(OC1=O)([CH]2C(C46(CC(CC[CH]34)C5(OC5)(C6)))C([O-])=O))

InChI: InChI=1S/C19H24O5/c1-16-5-2-6-19(24-15(16)22)11-4-3-10-7-17(11,8-18(10)9-23-18)12(13(16)19)14(20)21/h10-13H,2-9H2,1H3,(H,20,21)/p-1/t10-,11-,12-,13-,16+,17-,18+,19?/m1/s1

InChIKey: InChIKey=PXYCXLNQKAEBRB-XAGBHBTISA-M

Unification Links: PubChem:46173298

Standard Gibbs Free Energy of Change Formation (ΔfG in kcal/mol): 73.423706 Inferred by computational analysis [Latendresse13]

Reactions known to consume the compound:

gibberellin inactivation III (epoxidation) :
16α, 17-epoxy gibberellin A9 → 16, 17-dihydro-16α, 17-dihydroxy gibberellin A9

linoleate biosynthesis I (plants) :
oleoyl-CoA + a lipid + H+ → a lipid oleoyl-group + coenzyme A

Reactions known to produce the compound:

gibberellin inactivation III (epoxidation) :
gibberellin A9 + NAD(P)H + oxygen + H+16α, 17-epoxy gibberellin A9 + NAD(P)+ + H2O

Not in pathways:
a prohormone + H2O → a hormone

glutathione redox reactions I :
a lipid hydroperoxide + 2 glutathione + H+a lipid + glutathione disulfide + 2 H2O

Credits:
Created 15-Apr-2010 by Dreher KA , TAIR


References

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."

Zhu06a: Zhu Y, Nomura T, Xu Y, Zhang Y, Peng Y, Mao B, Hanada A, Zhou H, Wang R, Li P, Zhu X, Mander LN, Kamiya Y, Yamaguchi S, He Z (2006). "ELONGATED UPPERMOST INTERNODE encodes a cytochrome P450 monooxygenase that epoxidizes gibberellins in a novel deactivation reaction in rice." Plant Cell 18(2);442-56. PMID: 16399803


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 18.5 on Wed Dec 17, 2014, biocyc13.