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discounted EARLY registration ends Dec 31, 2014
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discounted EARLY registration ends Dec 31, 2014
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discounted EARLY registration ends Dec 31, 2014
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MetaCyc Compound: all-trans-dodecaprenyl diphosphate

Synonyms: dodecaprenyl diphosphate

Superclasses: a lipid an isoprenoid an isoprenoid phosphate an isoprenoid diphosphate an all-trans-polyisoprenyl diphosphate

Summary:
For polyisoprenols and polyisoprenyl phosphates nomenclature, see an isoprenoid.

Chemical Formula: C60H97O7P2

Molecular Weight: 992.37 Daltons

Monoisotopic Molecular Weight: 994.6944285847 Daltons

SMILES: CC(=CCCC(=CCCC(=CCCC(=CCCC(=CCCC(=CCCC(=CCCC(=CCCC(=CCCC(=CCCC(=CCCC(=CCOP(OP(=O)([O-])[O-])([O-])=O)C)C)C)C)C)C)C)C)C)C)C)C

InChI: InChI=1S/C60H100O7P2/c1-49(2)25-14-26-50(3)27-15-28-51(4)29-16-30-52(5)31-17-32-53(6)33-18-34-54(7)35-19-36-55(8)37-20-38-56(9)39-21-40-57(10)41-22-42-58(11)43-23-44-59(12)45-24-46-60(13)47-48-66-69(64,65)67-68(61,62)63/h25,27,29,31,33,35,37,39,41,43,45,47H,14-24,26,28,30,32,34,36,38,40,42,44,46,48H2,1-13H3,(H,64,65)(H2,61,62,63)/p-3/b50-27+,51-29+,52-31+,53-33+,54-35+,55-37+,56-39+,57-41+,58-43+,59-45+,60-47+

InChIKey: InChIKey=WURMRKUXTPWSRM-GNZYJLLNSA-K

Unification Links: ChEBI:8307 , HMDB:HMDB12217 , KEGG:C05847 , PubChem:25246060

Standard Gibbs Free Energy of Change Formation (ΔfG in kcal/mol): 863.30023 Inferred by computational analysis [Latendresse, 2013]

Reactions known to consume the compound:

menaquinol-12 biosynthesis :
all-trans-dodecaprenyl diphosphate + 1,4-dihydroxy-2-naphthoate + H+ → demethylmenaquinol-12 + CO2 + diphosphate

linoleate biosynthesis I (plants) :
oleoyl-CoA + a lipid + H+ → a lipid oleoyl-group + coenzyme A

Reactions known to produce the compound:

glutathione redox reactions I :
a lipid hydroperoxide + 2 glutathione + H+a lipid + glutathione disulfide + 2 H2O

In Reactions of unknown directionality:

dodecaprenyl diphosphate biosynthesis :
(2E,6E)-farnesyl diphosphate + 9 isopentenyl diphosphate = all-trans-dodecaprenyl diphosphate + 9 diphosphate

Not in pathways:
an all-trans-polyisoprenyl diphosphate + 1,4-dihydroxy-2-naphthoate + H+ = CO2 + a demethylmenaquinol + diphosphate


an isoprenoid diphosphate + 4-hydroxybenzoate = a 4-hydroxy-3-polyprenylbenzoate + diphosphate


References

Latendresse, 2013: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 18.5 on Sat Nov 22, 2014, biocyc13.