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MetaCyc Compound Class: L-rhamnofuranose

Superclasses: all carbohydratesa carbohydratea glycana sugara monosaccharidea hexosean L-hexoseL-rhamnose
all carbohydratesa carbohydratea glycana sugara monosaccharidea hexoserhamnoseL-rhamnose

L-rhamnofuranose compound structure

Chemical Formula: C6H12O5

Instances:
α-L-rhamnofuranose,
β-L-rhamnofuranose

Molecular Weight: 164.16 Daltons

Monoisotopic Molecular Weight: 164.0684734957 Daltons

SMILES: CC([CH]1(C(C(O)C(O1)O)O))O

InChI: InChI=1S/C6H12O5/c1-2(7)5-3(8)4(9)6(10)11-5/h2-10H,1H3/t2-,3-,4+,5-,6?/m0/s1

InChIKey: InChIKey=AFNUZVCFKQUDBJ-ZZWDRFIYSA-N

Unification Links: ChEBI:16935, ChemSpider:388788, KEGG:C02431, PubChem:439724

Standard Gibbs Free Energy of Change Formation (ΔfG in kcal/mol): -58.55656Inferred by computational analysis [Latendresse13]

Reactions known to consume the compound:

L-rhamnose degradation II , L-rhamnose degradation III :
L-rhamnofuranose + NAD(P)+ → L-rhamnono-1,4-lactone + NAD(P)H + H+

Reactions known to produce the compound:

Not in pathways:
a protopanaxatriol-type ginsenoside with two glycosyl residues at position 6 + 2 H2O → a protopanaxatriol-type ginsenoside with no glycosidic modification at position 6 + a monosaccharide + D-glucopyranose
a protopanaxadiol-type ginsenoside with two glycosyl residues at position 20 + H2O → a protopanaxadiol-type ginsenoside with a single glucosyl residue at position 20 + a monosaccharide

Not in pathways:
a thioglucoside + H2O → a sugar + a thiol
a sugar phosphate + H2O → a sugar + phosphate
glycosyl-N-acylsphingosine + H2O → a ceramide + a sugar

Reactions known to both consume and produce the compound:

L-rhamnose degradation II :
L-rhamnopyranose ↔ L-rhamnofuranose
L-rhamnofuranose + NAD+ ↔ L-rhamnono-1,4-lactone + NADH + H+

L-rhamnose degradation III :
L-rhamnopyranose ↔ L-rhamnofuranose
L-rhamnofuranose + NAD+ ↔ L-rhamnono-1,4-lactone + NADH + H+

In Reactions of unknown directionality:

Not in pathways:
L-rhamnofuranose + NADP+ = L-rhamnono-1,4-lactone + NADPH + H+

Not in pathways:
a protopanaxatriol-type ginsenoside with two glycosyl residues at position 6 + H2O = a protopanaxatriol-type ginsenoside with a single glucosyl at position 6 + a monosaccharide

In Transport reactions:
L-rhamnose[periplasm] + H+[periplasm]L-rhamnose[cytosol] + H+[cytosol],
a monosaccharide[extracellular space] + ATP + H2O ↔ a monosaccharide[cytosol] + ADP + phosphate,
a [PTS enzyme I]-Nπ-phospho-L-histidine + a sugar[out] → a [PTS enzyme I]-L-histidine + a sugar phosphate[in]


References

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by Pathway Tools version 19.5 (software by SRI International) on Mon Feb 8, 2016, biocyc13.