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Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
BioCyc websites down
12/28 - 12/31
for maintenance.
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MetaCyc Compound Class: L-rhamnofuranose

Superclasses: all carbohydrates a carbohydrate a glycan a sugar a monosaccharide a hexose an L-hexose L-rhamnose
all carbohydrates a carbohydrate a glycan a sugar a monosaccharide a hexose rhamnose L-rhamnose

Chemical Formula: C6H12O5

Instances:
α-L-rhamnofuranose ,
β-L-rhamnofuranose

Molecular Weight: 164.16 Daltons

Monoisotopic Molecular Weight: 164.0684734957 Daltons

SMILES: CC([CH]1(C(C(O)C(O1)O)O))O

InChI: InChI=1S/C6H12O5/c1-2(7)5-3(8)4(9)6(10)11-5/h2-10H,1H3/t2-,3-,4+,5-,6?/m0/s1

InChIKey: InChIKey=AFNUZVCFKQUDBJ-ZZWDRFIYSA-N

Unification Links: ChEBI:16935 , ChemSpider:388788 , KEGG:C02431 , PubChem:439724

Standard Gibbs Free Energy of Change Formation (ΔfG in kcal/mol): -58.55656 Inferred by computational analysis [Latendresse13]

Reactions known to consume the compound:

L-rhamnose degradation II , L-rhamnose degradation III :
L-rhamnofuranose + NAD(P)+ → L-rhamnono-1,4-lactone + NAD(P)H + H+

Reactions known to produce the compound:

Not in pathways:
a protopanaxatriol-type ginsenoside with two glycosyl residues at position 6 + 2 H2O → a protopanaxatriol-type ginsenoside with no glycosidic modification at position 6 + a monosaccharide + D-glucopyranose
a protopanaxadiol-type ginsenoside with two glycosyl residues at position 20 + H2O → a protopanaxadiol-type ginsenoside with a single glucosyl residue at position 20 + a monosaccharide


a thioglucoside + H2O → a sugar + a thiol
a sugar phosphate + H2O → a sugar + phosphate
glycosyl-N-acylsphingosine + H2O → a ceramide + a sugar


an N-acetyl-β-D-galactosalaminyl-[glycan] + H2O → a glycan + N-acetyl-β-D-galactosamine

Reactions known to both consume and produce the compound:

L-rhamnose degradation II :
L-rhamnopyranose ↔ L-rhamnofuranose
L-rhamnofuranose + NAD+ ↔ L-rhamnono-1,4-lactone + NADH + H+

L-rhamnose degradation III :
L-rhamnopyranose ↔ L-rhamnofuranose
L-rhamnofuranose + NAD+ ↔ L-rhamnono-1,4-lactone + NADH + H+

In Reactions of unknown directionality:

Not in pathways:
L-rhamnofuranose + NADP+ = L-rhamnono-1,4-lactone + NADPH + H+


a protopanaxatriol-type ginsenoside with two glycosyl residues at position 6 + H2O = a protopanaxatriol-type ginsenoside with a single glucosyl at position 6 + a monosaccharide

In Transport reactions:
L-rhamnose[periplasmic space] + H+[periplasmic space]L-rhamnose[cytosol] + H+[cytosol] ,
a monosaccharide[extracellular space] + ATP + H2O ↔ a monosaccharide[cytosol] + ADP + phosphate ,
a [PTS enzyme I]-Nπ-phospho-L-histidine + a sugar[out] → a [PTS enzyme I]-L-histidine + a sugar phosphate[in]


References

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 18.5 on Fri Dec 19, 2014, biocyc14.