Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
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MetaCyc Reaction: 1.1.1.223

Superclasses: Reactions Classified By Conversion Type Simple Reactions Chemical Reactions
Reactions Classified By Substrate Small-Molecule Reactions

EC Number: 1.1.1.223

Enzymes and Genes:
(-)-isopiperitenol dehydrogenase Inferred from experiment : ISPD ( Mentha x piperita )

In Pathway: menthol biosynthesis

The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the Enzyme Commission system.

Most BioCyc compounds have been protonated to a reference pH value of 7.3, and some reactions have been computationally balanced for hydrogen by adding free protons. Please see the PGDB Concepts Guide for more information.

Mass balance status: Balanced.

Enzyme Commission Primary Name: isopiperitenol dehydrogenase

Standard Gibbs Free Energy (ΔrG in kcal/mol): -1.9282074 Inferred by computational analysis [Latendresse13]

Enzyme Commission Summary:
Acts on (-)-trans-isopiperitenol, (+)-trans-piperitenol and (+)-trans-pulegol. Involved in the biosynthesis of menthol and related monoterpenes in peppermint (Mentha piperita) leaves.

Citations: [Kjonaas85]

Gene-Reaction Schematic: ?

Unification Links: KEGG:R03261 , Rhea:20860

Relationship Links: BRENDA:EC:1.1.1.223 , ENZYME:EC:1.1.1.223 , IUBMB-ExplorEnz:EC:1.1.1.223


References

Kjonaas85: Kjonaas RB, Venkatachalam KV, Croteau R (1985). "Metabolism of monoterpenes: oxidation of isopiperitenol to isopiperitenone, and subsequent isomerization to piperitenone by soluble enzyme preparations from peppermint (Mentha piperita) leaves." Arch Biochem Biophys 238(1);49-60. PMID: 3885858

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 18.5 on Fri Nov 28, 2014, biocyc14.