|Superclasses:||Reactions Classified By Conversion Type → Simple Reactions → Chemical Reactions|
|Reactions Classified By Substrate → Small-Molecule Reactions|
EC Number: 184.108.40.206
Enzymes and Genes:
|Petunia x hybrida:||acyl-CoA ω-hydroxylase: CYP86A22|
In Pathway: stigma estolide biosynthesis
The direction shown, i.e. which substrates are on the left and right sides, is in accordance with the direction in which it was curated.
Most BioCyc compounds have been protonated to a reference pH value of 7.3. Please see the PGDB Concepts Guide for more information.
Mass balance status: Balanced.
Enzyme Commission Primary Name: long-chain acyl-CoA ω-monooxygenase
Enzyme Commission Synonyms: long-chain acyl-CoA ω-hydroxylase, CYP86A22 (gene name), CYP52M1 (gene name)
Standard Gibbs Free Energy (ΔrG'°): -88.65057 kcal/mol [Latendresse13]
Enzyme Commission Summary:
The enzymes from solanaceous plants are involved in the biosynthesis of stigmatic estolide, a lipid-based polyester that forms a major component of the exudate.
Han10b: Han J, Clement JM, Li J, King A, Ng S, Jaworski JG (2010). "The cytochrome P450 CYP86A22 is a fatty acyl-CoA omega-hydroxylase essential for Estolide synthesis in the stigma of Petunia hybrida." J Biol Chem 285(6);3986-96. PMID: 19940120
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