Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
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MetaCyc Reaction: [no EC number assigned]

Superclasses: Reactions Classified By Conversion Type Simple Reactions Chemical Reactions
Reactions Classified By Substrate Small-Molecule Reactions

In Pathway: phenylphenalenone biosynthesis

The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the direction in which it was curated.

Mass balance status: Marked as unbalanced.

Standard Gibbs Free Energy (ΔrG in kcal/mol): -77.691246 Inferred by computational analysis [Latendresse13]

Summary:
The conversion of 1-phenyl-7-(3,4-dihydroxyphenyl)-hepta-1,3-dien-5-one to anigorufone was confirmed by feeding a [2-C13]-radiolabeled form of the reactant to Anigozanthos preissii root cultures [Holscher95]. This Diels-Alder type reaction is proposed to be a necessary intermediate step [Holscher95].

Credits:
Created 22-Feb-2010 by Dreher KA , TAIR


References

Holscher95: Holscher, D., Schneider, B. (1995). "A diarylheptanoid intermediate in the biosynthesis of phenylphenalenones in Anigozanthos preissii." Journal of the Chemical Society Chemical Communications, 525-526.

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 18.5 on Thu Dec 18, 2014, BIOCYC14B.