|Superclasses:||Reactions Classified By Conversion Type → Simple Reactions → Chemical Reactions|
|Reactions Classified By Substrate → Small-Molecule Reactions|
In Pathway: phenylphenalenone biosynthesis
The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the direction in which it was curated.
Mass balance status: Marked as unbalanced.
Standard Gibbs Free Energy (ΔrG'° in kcal/mol): -77.691246 [Latendresse13]
The conversion of 1-phenyl-7-(3,4-dihydroxyphenyl)-hepta-1,3-dien-5-one to anigorufone was confirmed by feeding a [2-C13]-radiolabeled form of the reactant to Anigozanthos preissii root cultures [Holscher95]. This Diels-Alder type reaction is proposed to be a necessary intermediate step [Holscher95].
Holscher95: Holscher, D., Schneider, B. (1995). "A diarylheptanoid intermediate in the biosynthesis of phenylphenalenones in Anigozanthos preissii." Journal of the Chemical Society Chemical Communications, 525-526.
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