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MetaCyc Reaction: [no EC number assigned]

Superclasses: Reactions Classified By Conversion TypeSimple ReactionsChemical Reactions
Reactions Classified By SubstrateSmall-Molecule Reactions

In Pathway: phenylphenalenone biosynthesis

The direction shown, i.e. which substrates are on the left and right sides, is in accordance with the direction in which it was curated.

Mass balance status: Marked as unbalanced.

Standard Gibbs Free Energy (ΔrG in kcal/mol): -77.691246Inferred by computational analysis [Latendresse13]

Summary:
The conversion of 1-phenyl-7-(3,4-dihydroxyphenyl)-hepta-1,3-dien-5-one to anigorufone was confirmed by feeding a [2-C13]-radiolabeled form of the reactant to Anigozanthos preissii root cultures [Holscher95]. This Diels-Alder type reaction is proposed to be a necessary intermediate step [Holscher95].

Credits:
Created 22-Feb-2010 by Dreher KA, TAIR


References

Holscher95: Holscher, D., Schneider, B. (1995). "A diarylheptanoid intermediate in the biosynthesis of phenylphenalenones in Anigozanthos preissii." Journal of the Chemical Society Chemical Communications, 525-526.

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by Pathway Tools version 19.5 (software by SRI International) on Fri Apr 29, 2016, biocyc11.