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MetaCyc Reaction: 4.2.3.57

Superclasses: Reactions Classified By Conversion Type Simple Reactions Chemical Reactions
Reactions Classified By Substrate Small-Molecule Reactions

EC Number: 4.2.3.57

Enzymes and Genes:

Abies grandis : δ-selinene synthase Inferred from experiment : f-δsel1
Arabidopsis thaliana col : (-)-β-caryophyllene synthase Inferred from experiment : AT5G23960
Artemisia annua : beta-caryophyllene synthase Inferred from experiment : QHS1
Cucumis sativus : beta-caryophyllene synthase Inferred from experiment : bcp
Oryza sativa : (E)-beta-caryophyllene/beta-elemene synthase Inferred from experiment : OsTPS3
Solanum lycopersicum : caryophyllene synthase Inferred from experiment : CAHS
Zea luxurians : (E)-beta-caryophyllene synthase Inferred from experiment : tps23
Zea mays : (E)-beta-caryophyllene synthase Inferred from experiment : tps23
Zea mays huehuetenangensis : (E)-beta-caryophyllene synthase Inferred from experiment : TPS23
Zingiber zerumbet : alpha-humulene synthase Inferred from experiment : zss1

In Pathway: oleoresin sesquiterpene volatiles biosynthesis , β-caryophyllene biosynthesis

The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the direction in which it was curated.

Mass balance status: Balanced.

Enzyme Commission Primary Name: (-)-β-caryophyllene synthase

Enzyme Commission Synonyms: β-caryophyllene synthase, (2E,6E)-farnesyl-diphosphate diphosphate-lyase (caryophyllene-forming)

Standard Gibbs Free Energy (ΔrG in kcal/mol): -27.619995 Inferred by computational analysis [Latendresse13]

Enzyme Commission Summary:
Widely distributed in higher plants, cf.EC 4.2.3.89 (+)-β-caryophyllene synthase.

Citations: [Cai02]

Gene-Reaction Schematic: ?

Gene-Reaction Schematic

Unification Links: KEGG:R08541 , Rhea:28294

Relationship Links: BRENDA:EC:4.2.3.57 , ENZYME:EC:4.2.3.57 , IUBMB-ExplorEnz:EC:4.2.3.57

Credits:
Revised 21-Oct-2011 by Caspi R , SRI International


References

Cai02: Cai Y, Jia JW, Crock J, Lin ZX, Chen XY, Croteau R (2002). "A cDNA clone for beta-caryophyllene synthase from Artemisia annua." Phytochemistry 61(5);523-9. PMID: 12409018

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 19.0 on Tue Jun 30, 2015, biocyc14.