Metabolic Modeling Tutorial
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Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
Metabolic Modeling Tutorial
discounted EARLY registration ends Dec 31, 2014
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MetaCyc Reaction: 3.1.7.11

Superclasses: Reactions Classified By Conversion Type Simple Reactions Chemical Reactions
Reactions Classified By Substrate Small-Molecule Reactions

EC Number: 3.1.7.11

Enzymes and Genes:
P-geraniol synthase Inferred from experiment : PfTps-PL ( Perilla frutescens )
C-geraniol synthase Inferred from experiment : PcTps-C ( Perilla citriodora )
geraniol synthase Inferred from experiment : GES ( Ocimum basilicum )
geraniol synthase Inferred from experiment : GES ( Cinnamomum tenuipile )
geraniol synthase Inferred from experiment : TPS1 ( Zea mays )

In Pathway: geraniol and geranial biosynthesis , secologanin and strictosidine biosynthesis

The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the Enzyme Commission system.

Mass balance status: Balanced.

Enzyme Commission Primary Name: geranyl diphosphate diphosphatase

Enzyme Commission Synonyms: geraniol synthase, geranyl pyrophosphate pyrophosphatase, GES, CtGES

Standard Gibbs Free Energy (ΔrG in kcal/mol): -3.742981 Inferred by computational analysis [Latendresse13]

Enzyme Commission Summary:
Isolated from Ocimum basilicum (basil) and Cinnamomum tenuipile (camphor tree). Requires Mg2+ or Mn2+. The mechanism involves a geranyl cation [Iijima04]. Neryl diphosphate is hydrolysed more slowly. May be the same as EC 3.1.7.3 monoterpenyl-diphosphatase.

Citations: [Yang05a]

Gene-Reaction Schematic: ?

Unification Links: KEGG:R08396 , Rhea:32682

Relationship Links: BRENDA:EC:3.1.7.11 , ENZYME:EC:3.1.7.11 , IUBMB-ExplorEnz:EC:3.1.7.11

Credits:
Revised 23-Jan-2012 by Caspi R , SRI International


References

Iijima04: Iijima Y, Gang DR, Fridman E, Lewinsohn E, Pichersky E (2004). "Characterization of geraniol synthase from the peltate glands of sweet basil." Plant Physiol 134(1);370-9. PMID: 14657409

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."

Yang05a: Yang T, Li J, Wang HX, Zeng Y (2005). "A geraniol-synthase gene from Cinnamomum tenuipilum." Phytochemistry 66(3);285-93. PMID: 15680985


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 18.5 on Tue Nov 25, 2014, BIOCYC13A.