|Superclasses:||Reactions Classified By Conversion Type → Simple Reactions → Chemical Reactions|
|Reactions Classified By Substrate → Small-Molecule Reactions|
EC Number: 18.104.22.168
Enzymes and Genes:
P-geraniol synthase : PfTps-PL ( Perilla frutescens )
C-geraniol synthase : PcTps-C ( Perilla citriodora )
geraniol synthase : GES ( Ocimum basilicum )
geraniol synthase : GES ( Cinnamomum tenuipile )
geraniol synthase : TPS1 ( Zea mays )
The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the Enzyme Commission system.
Mass balance status: Balanced.
Enzyme Commission Primary Name: geranyl diphosphate diphosphatase
Enzyme Commission Synonyms: geraniol synthase, geranyl pyrophosphate pyrophosphatase, GES, CtGES
Standard Gibbs Free Energy (ΔrG'° in kcal/mol): -3.742981 [Latendresse13]
Enzyme Commission Summary:
Isolated from Ocimum basilicum (basil) and Cinnamomum tenuipile (camphor tree). Requires Mg2+ or Mn2+. The mechanism involves a geranyl cation [Iijima04]. Neryl diphosphate is hydrolysed more slowly. May be the same as EC 22.214.171.124 monoterpenyl-diphosphatase.
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