|Superclasses:||Reactions Classified By Conversion Type → Simple Reactions → Chemical Reactions|
|Reactions Classified By Substrate → Small-Molecule Reactions|
EC Number: 1.14.13.-
Enzymes and Genes:
|Arabidopsis thaliana col:||fatty acid ω-hydroxylase: CYP94C1|
long-chain fatty acid ω-hydroxylase: CYP704B1
|Glycine max:||long-chain fatty acid ω-hydroxylase|
|Starmerella bombicola:||long-chain fatty acid ω/(ω-1) hydroxylase: CYP52M1|
In Pathway: cutin biosynthesis
The direction shown, i.e. which substrates are on the left and right sides, is in accordance with the direction in which it was curated.
Most BioCyc compounds have been protonated to a reference pH value of 7.3. Please see the PGDB Concepts Guide for more information.
Mass balance status: Balanced.
Enzyme Commission Primary Name: 1.14.13 -- With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
Standard Gibbs Free Energy (ΔrG'° in kcal/mol): -88.65054 [Latendresse13]
Instance reactions of [a long-chain fatty acid + NADPH + oxygen + H+ → an ω-hydroxy long-chain fatty acid + NADP+ + H2O] (220.127.116.11):
i1: docosahexaenoate + NADPH + H+ + oxygen → 22-hydroxydocosahexaenoate + NADP+ + H2O (18.104.22.168)
i2: stearate + NADPH + oxygen + H+ → 18-hydroxystearate + NADP+ + H2O (22.214.171.124)
i3: palmitate + NADPH + oxygen + H+ → 16-hydroxypalmitate + NADP+ + H2O (126.96.36.199)
i4: oleate + NADPH + oxygen + H+ → 18-hydroxyoleate + NADP+ + H2O (188.8.131.52)
i5: (9R,10S)-dihydroxystearate + NADPH + oxygen + H+ → 9,10,18-trihydroxystearate + NADP+ + H2O (1.14.13.-)
i6: 9,10-epoxystearate + NADPH + oxygen + H+ → 9,10-epoxy-18-hydroxystearate + NADP+ + H2O (1.14.13.-)
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