|Superclasses:||Reactions Classified By Conversion Type → Simple Reactions → Chemical Reactions|
|Reactions Classified By Substrate → Small-Molecule Reactions|
EC Number: 1.14.13.-
Enzymes and Genes:
|Arabidopsis thaliana col :||fatty acid ω-hydroxylase
long-chain fatty acid ω-hydroxylase : CYP704B1
|Glycine max :||long-chain fatty acid ω-hydroxylase
|Starmerella bombicola :||long-chain fatty acid ω/(ω-1) hydroxylase
In Pathway: cutin biosynthesis
The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the direction in which it was curated.
Most BioCyc compounds have been protonated to a reference pH value of 7.3, and some reactions have been computationally balanced for hydrogen by adding free protons. Please see the PGDB Concepts Guide for more information.
Mass balance status: Balanced.
Enzyme Commission Primary Name: 1.14.13 -- With NADH or NADPH as one donor, and incorporation of one atom of oxygen
Standard Gibbs Free Energy (ΔrG'° in kcal/mol): -88.65054 [Latendresse13]
Instance reactions of [a long-chain fatty acid + NADPH + oxygen + H+ → an ω-hydroxy long-chain fatty acid + NADP+ + H2O] (1.14.13.cs):
i1: palmitate + NADPH + oxygen + H+ → 16-hydroxypalmitate + NADP+ + H2O (1.14.13.cs)
i2: (9R,10S)-dihydroxystearate + NADPH + oxygen + H+ → 9,10,18-trihydroxystearate + NADP+ + H2O (1.14.13.-)
i3: docosahexaenoate + NADPH + H+ + oxygen → 22-hydroxydocosahexaenoate + NADP+ + H2O (188.8.131.52)
i4: oleate + NADPH + oxygen + H+ → 18-hydroxyoleate + NADP+ + H2O (1.14.13.cs)
i5: 9,10-epoxystearate + NADPH + oxygen + H+ → 9,10-epoxy-18-hydroxystearate + NADP+ + H2O (1.14.13.-)
i6: stearate + NADPH + oxygen + H+ → 18-hydroxystearate + NADP+ + H2O (1.14.13.cs)
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