MetaCyc Reaction: 1.14.13.-

Superclasses: Reactions Classified By Conversion Type Simple Reactions Chemical Reactions Composite Reactions
Reactions Classified By Conversion Type Simple Reactions Chemical Reactions
Reactions Classified By Substrate Small-Molecule Reactions

EC Number: 1.14.13.-

Enzymes and Genes:

Arabidopsis thaliana col : CYP79F1 monooxygenase Inferred from experiment : At1g16410
CYP79F2 monooxygenase Inferred from experiment : At1g16400

In Pathway: glucosinolate biosynthesis from hexahomomethionine

The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the direction in which it was curated.

Most BioCyc compounds have been protonated to a reference pH value of 7.3, and some reactions have been computationally balanced for hydrogen by adding free protons. Please see the PGDB Concepts Guide for more information.

Mass balance status: Balanced.

Enzyme Commission Primary Name: 1.14.13 -- With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor

hexahomomethionine + NADPH + oxygen → N-hydroxyhexahomomethioniate + NADP+ + H2O ,
N-hydroxyhexahomomethioniate + NADPH + oxygen + H+N,N-dihydroxyhexahomomethioniate + NADP+ + H2O ,
N,N-dihydroxyhexahomomethioniate + H+ = 9-methylthiononanaldoxime + CO2 + H2O

Standard Gibbs Free Energy (ΔrG in kcal/mol): -198.21808 Inferred by computational analysis [Latendresse13]

Gene-Reaction Schematic: ?

Gene-Reaction Schematic

Unification Links: KEGG:R08675 , Rhea:33298


Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."

Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 19.0 on Thu Oct 8, 2015, biocyc13.